Eurasian Journal of Soil Science

Volume 9, Issue 3, Jul 2020, Pages 231-241
DOI: 10.18393/ejss.734601
Stable URL: http://ejss.fess.org/10.18393/ejss.734601
Copyright © 2020 The authors and Federation of Eurasian Soil Science Societies



Assessment of extraction methods for studying the fractional composition of Cu and Zn in uncontaminated and contaminated soils

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Burachevskaya,M., Minkina,T., Bauer,T., Mandzhieva,S., Gülser,C., Kızılkaya,R., Sushkova,S., Rajput,V., 2020. Assessment of extraction methods for studying the fractional composition of Cu and Zn in uncontaminated and contaminated soils. Eurasian J Soil Sci 9(3):231-241. DOI : 10.18393/ejss.734601
Burachevskaya,M.Minkina,T.,Bauer,T.Mandzhieva,S.Gülser,C.Kızılkaya,R.Sushkova,S.,& Rajput,V. Assessment of extraction methods for studying the fractional composition of Cu and Zn in uncontaminated and contaminated soils Eurasian Journal of Soil Science, 9(3):231-241. DOI : 10.18393/ejss.734601
Burachevskaya,M.Minkina,T.,Bauer,T.Mandzhieva,S.Gülser,C.Kızılkaya,R.Sushkova,S., and ,Rajput,V."Assessment of extraction methods for studying the fractional composition of Cu and Zn in uncontaminated and contaminated soils" Eurasian Journal of Soil Science, 9.3 (2020):231-241. DOI : 10.18393/ejss.734601
Burachevskaya,M.Minkina,T.,Bauer,T.Mandzhieva,S.Gülser,C.Kızılkaya,R.Sushkova,S., and ,Rajput,V. "Assessment of extraction methods for studying the fractional composition of Cu and Zn in uncontaminated and contaminated soils" Eurasian Journal of Soil Science,9(Jul 2020):231-241 DOI : 10.18393/ejss.734601
M,Burachevskaya.T,Minkina.T,Bauer.S,Mandzhieva.C,Gülser.R,Kızılkaya.S,Sushkova.V,Rajput "Assessment of extraction methods for studying the fractional composition of Cu and Zn in uncontaminated and contaminated soils" Eurasian J. Soil Sci, vol.9, no.3, pp.231-241 (Jul 2020), DOI : 10.18393/ejss.734601
Burachevskaya,Marina ;Minkina,Tatiana ;Bauer,Tatiana ;Mandzhieva,Saglara ;Gülser,Coşkun ;Kızılkaya,Rıdvan ;Sushkova,Svetlana ;Rajput,Vishnu Assessment of extraction methods for studying the fractional composition of Cu and Zn in uncontaminated and contaminated soils. Eurasian Journal of Soil Science, (2020),9.3:231-241. DOI : 10.18393/ejss.734601

How to cite

Burachevskaya, M., Minkina, T., Bauer, T., Mandzhieva, S., Gülser, C., Kızılkaya, R., Sushkova, S., Rajput, V., 2020. Assessment of extraction methods for studying the fractional composition of Cu and Zn in uncontaminated and contaminated soils. Eurasian J. Soil Sci. 9(3): 231-241. DOI : 10.18393/ejss.734601

Author information

Marina Burachevskaya , Southern Federal University, Rostov-on-Don, Russia
Tatiana Minkina , Southern Federal University, Rostov-on-Don, Russia Rostov-on-Don, Russia
Tatiana Bauer , Southern Federal University, Rostov-on-Don, Russia
Saglara Mandzhieva , Southern Federal University, Rostov-on-Don, Russia
Coşkun Gülser , Ondokuz Mayıs University, Faculty of Agriculture, Department of Soil Science and Plant Nutrition, Samsun, Turkey
Rıdvan Kızılkaya , Ondokuz Mayıs University, Faculty of Agriculture, Department of Soil Science and Plant Nutrition, Samsun, Turkey
Svetlana Sushkova , Southern Federal University, Rostov-on-Don, Russia
Vishnu Rajput , Southern Federal University, Rostov-on-Don, Russia

Publication information

Article first published online : 08 May 2020
Manuscript Accepted : 05 May 2020
Manuscript Received: 15 Aug 2019
DOI: 10.18393/ejss.734601
Stable URL: http://ejss.fesss.org/10.18393/ejss.734601

Abstract

This study is aimed at elucidating the fractionation of Cu and Zn in Haplic Chernozem and its alteration under the contamination to evaluate the extraction selectivity of different extractants and thus the efficiency of three sequential extraction schemes (Tessier and McLaren five-step and modified BCR three-step methods). General trends in the distribution of Cu and Zn speciations revealed with these three fractionation schemes suggest that they can be applied for the soils and the obtained results can be compared. Low mobility of potentially toxic metals (PTM) in the studied soil is suggested not only by their high content in residual fraction, but also by low contents of exchangeable and carbonate bound fractions (not more than 4-5 % Cu and 5-7 % Zn in the first two fractions). The highest contribution to the absorption and retention of Cu delivered from anthropogenic sources is made by organic matter and sesquioxides (up to 29 %); for Zn, by the nonsilicate Fe and Mn compounds (up to 25 %). However, the pattern of PTM extraction from soils varies during the application of different fractionation methods. The Tessier method is distinguished by a higher extractability relative to organic matter and sesquioxides. Therefore, this method is more informative for the contaminated soils. The McLaren method makes it possible to track the weakly bound species of compounds without the risk of involving other soil components. The BCR method is marked by simplicity of application and, therefore, recommended only for the noncalcic or low-calcic soils.

Keywords

Assessment, soil, trace metals, selective sequential schemes, mobility, metal forms.

Corresponding author

References

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Abstract

This study is aimed at elucidating the fractionation of Cu and Zn in Haplic Chernozem and its alteration under the contamination to evaluate the extraction selectivity of different extractants and thus the efficiency of three sequential extraction schemes (Tessier and McLaren five-step and modified BCR three-step methods). General trends in the distribution of Cu and Zn speciations revealed with these three fractionation schemes suggest that they can be applied for the soils and the obtained results can be compared. Low mobility of potentially toxic metals (PTM) in the studied soil is suggested not only by their high content in residual fraction, but also by low contents of exchangeable and carbonate bound fractions (not more than 4-5 % Cu and 5-7 % Zn in the first two fractions). The highest contribution to the absorption and retention of Cu delivered from anthropogenic sources is made by organic matter and sesquioxides (up to 29 %); for Zn, by the nonsilicate Fe and Mn compounds (up to 25 %). However, the pattern of PTM extraction from soils varies during the application of different fractionation methods. The Tessier method is distinguished by a higher extractability relative to organic matter and sesquioxides. Therefore, this method is more informative for the contaminated soils. The McLaren method makes it possible to track the weakly bound species of compounds without the risk of involving other soil components. The BCR method is marked by simplicity of application and, therefore, recommended only for the noncalcic or low-calcic soils.

Keywords: Assessment, soil, trace metals, selective sequential schemes, mobility, metal forms.

References

Acosta, J.A., Gabarrón, M., Faz, A., Martínez-Martínez, S., Zornoza, R., Arocena, J.M., 2015. Influence of population density on the concentration and speciation of metals in the soil and street dust from urban areas. Chemosphere 134: 328-337.

Ahnstrom, Z.S., Parker, D.R., 1999. Development and assessment of a sequential extraction procedure for the fractionation of soil cadmium. Soil Science Society of America Journal 63(6): 1650-1658.

Al-Mur, B.A., 2020. Geochemical fractionation of heavy metals in sediments of the Red Sea, Saudi Arabia. Oceanologia 62(1): 31-44.

Anju, M., Banerjee, D.K., 2010. Comparison of two sequential extraction procedures for heavy metal partitioning in mine tailings. Chemosphere 78(11): 1393-1402.

Arenas-Lago, D., Andrade, M.L., Vega, F.A., Singh, B.R., 2016. TOF-SIMS and FE-SEM/EDS to verify the heavy metal fractionation in serpentinite quarry soils. Catena 136: 30-43.

Aten, C.F., Gupta, S.K., 1996. On heavy metals in soil; rationalization of extractions by dilute salt solutions, comparison of the extracted concentrations with uptake by ryegrass and lettuce, and the possible influence of pyrophosphate on plant uptake. Science of The Total Environment 178(1-3): 45-53.  

Baruah, N.K., Kotoky, P., Bhattacharyya, K.G., Borah, G.C., 1996.  Metal speciation in Jhanji River sediments. Science of the Total Environment 193(1): 1-12.

Bauer, T., Pinskii, D., Minkina, T., Mandzhieva, S., Burachevskaya, M., Kalinitchenko, V., Barakhov, A., 2018. Stabilization dynamics of easily and poorly soluble Zn compounds in the soil. Geochemistry: Exploration, Environment, Analysis 19(2): 184-192.

Clevenger, T.E., 1990. Use of sequential extraction to evaluate the heavy metals in mining wastes. Water, Air, & Soil Pollution 50: 241-254.

Coetzee, P.P., 1993. Determination and speciation of heavy metals in sediments of the Hartbeespoort Dam by sequential chemical extraction. Water SA 19: 291-300.

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